Real Madrid will face archrivals Barcelona at the Santiago Bernabéu on Sunday, October 26 at 15:15 GMT in the standout fixture of the 10th round of the Spanish league.
On Tuesday night, Madrid beat Levante 4-1 to extend their perfect start to the season, topping the table with 18 points from six games.
Barcelona, currently second with 13 points and one game in hand, will play Oviedo on Wednesday.
Last season, Barça got the better of Madrid in both league meetings, winning 4-0 and 4-3.
